Network modifiers in glass system: A Tribute to all who made me what I am today
Dear Friends,
This article is based on my understanding on the modifiers and the
way how our formed network changes. As these modifiers possess higher coordination
number and lower valency as discussed in article 50, where we know the rules
for glass formers in oxide glasses, I wish to correlate this concept with the
methods for survival in this inferior society. The role of glass formers are
really idealistic one. We can never be so pure/ in other words, the world doesn’t
accept ideals, they need someone who can dance to their tunes. The one who
makes you dance and the way how we look at the transparency dance to attain its
stability is because of these modifiers. Glass as we know it is an amorphous
solid with 3D network. This network has to be broken, that can be done by
modification, that responsibility is taken care by network modifiers. I wish to
list few interesting correlation on these modifiers on how they break our virtuousness.
The above periodic table indicates modifiers, Formers and intermediates in Glass system, it is interesting to know the family tree of glasses. This pictorial representation was done by my student Rojashree.
#1:
When you let a modifier (alkali atom), it occupies in interstitial sites and
creates non bridging oxides.
For example, let me call
network formers are those who trust and rely lot on us as you follow the rules
of being transparent and ethical in all terms. The morality might differ from
each individuals, they can be understood over a period of time and things can
be sorted out easily. Now, if the drift is settled between some other
individuals, things are going to be worse. As we know, he/she who tries to
resolve problem, will try to occupy upper hand and that would really be
damaging for two individuals who trust each other a lot. That trust is broken
because you have brought some joker/modifier inside to resolve the issue/ to
stabilize the relationship. This will really close some areas to explore
between two individuals. But the motto to maintain stability is achieved.
The pic indicates how network modifier takes stand in maintaining the stability of network
#2: Just because they are in,
their mobility has to be less, higher ones will incur conduction losses.
Just as I said, the one who
has resolved the issues should not be mobile in nature, if he is mobile, then
it reduces the transport properties/ in other words, we get distressed because
we have attained a stage like enough is enough, the material/device will be in
full conduction. The same happens even in relaxation loss. These things make
glass to explore arenas of conducting glasses, Lithium ion based glasses plays
prominent role in this field. As Lithium itself act as network modifier, as
this small little notorious fellow is highly active and mobile in nature. It is
often observed, when husband and wife fights, the kids act make them stable.
The role of modifier can be understood like this too. Sometimes, people choose
higher guys to keep them stable. It is often known that average age of a home
reduces the moment an infant/kid is in, the growth of kid is reflected on
mental stability of elders. That is how the life is all about..
This pic explains the occupancy of alkali network modifier in silicate glass
If just two points on modifying cation in glass gives us spectra of thoughts, imagine the world and the state of glass system
The opportunity for good system: If it has all the three qualities, control , transparency and stability. To achieve this, we need network modifiers.
The world of Network
modifiers in life is extremely important to enhance the glass stability.
The game of glass system is
also based on intermediates, these set of people are interesting, as they take
up positions of being part of former as well as modifier just like Parents, Siblings,
Best Friend Forever (BFF), Spouse. There are several modifiers in our life,
they may be teachers, friends, kids, a motivating renowned person/celebrity or
at times even a stranger whom we meet in life can correct the transparency what
we got, at times we must make use of these modifiers to build an efficient
glass system/ life system which is as transparent and complicated like glass.
The world seems to be really dangerous, but the stability of glass is always
higher because it knows how to handle it. There is limit for these modifiers
when it comes to intelligent Borate Glass System. This part is interesting one
to discuss, I would like to share it after four articles as I wish to dedicate
this article to all my network modifiers who made me stronger and stable materialistic
human being.